The problem is that UD is trying to mount the NFS mounts before the network is up:
Mar 29 11:13:14 BrownsBeast unassigned.devices: Error: Remote SMB/NFS server '192.168.2.230' is offline and share '192.168.2.230://volume1/video' cannot be mounted.
Mar 29 11:13:14 BrownsBeast unassigned.devices: Error: Remote SMB/NFS server '192.168.2.230' is offline and share '192.168.2.230://volume1/photos' cannot be mounted.
Mar 29 11:13:14 BrownsBeast emhttpd: Starting services...
Mar 29 11:13:14 BrownsBeast emhttpd: shcmd (63): /usr/local/sbin/mount_image '/mnt/user/system/docker/docker.img' /var/lib/docker 20
Mar 29 11:13:14 BrownsBeast kernel: BTRFS: device fsid e0a6a3d9-86b3-4967-8458-dc65511ef8d9 devid 1 transid 5602 /dev/loop2
Mar 29 11:13:14 BrownsBeast kernel: BTRFS info (device loop2): disk space caching is enabled
Mar 29 11:13:14 BrownsBeast kernel: BTRFS info (device loop2): has skinny extents
Mar 29 11:13:14 BrownsBeast root: Resize '/var/lib/docker' of 'max'
Mar 29 11:13:14 BrownsBeast kernel: BTRFS info (device loop2): new size for /dev/loop2 is 21474836480
Mar 29 11:13:14 BrownsBeast emhttpd: shcmd (65): /etc/rc.d/rc.docker start
Mar 29 11:13:14 BrownsBeast ntpd[1895]: Deleting interface #1 br0, 192.168.2.235#123, interface stats: received=11, sent=19, dropped=0, active_time=17 secs
Mar 29 11:13:14 BrownsBeast ntpd[1895]: 193.104.228.123 local addr 192.168.2.235 -> <null>
Mar 29 11:13:14 BrownsBeast ntpd[1895]: 212.99.225.86 local addr 192.168.2.235 -> <null>
Mar 29 11:13:14 BrownsBeast ntpd[1895]: 62.242.89.196 local addr 192.168.2.235 -> <null>
Mar 29 11:13:14 BrownsBeast ntpd[1895]: 92.246.24.225 local addr 192.168.2.235 -> <null>
Mar 29 11:13:14 BrownsBeast root: starting dockerd ...
Mar 29 11:13:14 BrownsBeast kernel: igb 0000:04:00.0 eth0: igb: eth0 NIC Link is Up 1000 Mbps Full Duplex, Flow Control: RX
Your network appears to be starting late in the boot up process.