vdisks are single large files, and can only exist on a single drive. They CAN however, be configured to appear larger on the inside, like a tardis. As you fill it, the real file size expands, but CAN'T flow across to other disks, and if you put more data than the disk is big, you will get error messages and crashes.
If your VM vdisk is on a drive or pool smaller than 6TB, you will have a bad time if you fill it.
Since you say you just created the VM fresh, I'd say nuke it and start over. Whether Steam will let you store files on a network share I don't know, so you will have to figure that out. If not, your only recourse would be to set up a vdisk on a drive or pool large enough to hold everything, or add vdisks and map them to paths internal to your VM.