Thank you PhAzE, but after completing this its still doing the same thing (and strangely the re-creating of the library took over 10hrs+ for 520 or so items, which seems incredibly long time to me compared to previous times Ive set up plex).
Pressing play directly from the movie wall, I get the fan art as a backdrop before it hangs - if I try to go to the fan art (before planning to press play as it were) I never get the chance as it hangs immediately with a grey screen and nothing at all appears indefinitely. Ive tried with 5 or 6 films with the same results.
I can still access any film directly from a command line using either IP or "tower" and the share name and that works - however before upgrading to 6.x I could also access each data disk directly via this method as well, but I cant now. No big deal, just thought it might be worth mentioning (like ip\flash, ip\disk2 etc , flash I can still access but none of the 8 data disks)
The GUI and plug in info all look reasonable and I'm guessing Unraid itself is pretty happy otherwise I wouldn't be able to resolve anything or GUI wouldn't be accessable.
It is doing a parity check at the moment (another 12 hrs to go ) but from what I recall this shouldn't stop me playing media (it hasn't in the past anyway) - when I mentioned it earlier this week no parity check was required / was running so this certainly wasn't the issue a couple of days ago