So the VM is up and accessible through Home Assistant IP and Port, but no it is currently is giving me the "Libvirt Service failed to start." error, I took the diagnostics while the error was present.
The Hassio VM is expendable because I have a snapshot of it, I am not worried about loss of data, I recreated the VM and pointed the the VHD and its right back to where it was.
I removed the libvirt img file and rebooted, it created the new libvirt image, I have not restarted again, I can do that now and report back in a few if it disappears again.