I have managed to improve matters a bit by upgrading to the latest Windows drivers from the Realtek website. I can now get a bandwidth of 1.62 Gbits/s after optimising some NIC parameters (the new driver provides far more control then Windows default driver which is dated 2015). This is still not ideal; transferring data to the new server from my backup Windows Server still saturates the resultant 1.62Gbit/s connection. There is a newer linux driver on the Realtek website but my understanding is that updating drivers outside the UNRAID release cycles is not recommended or supported.