I have to add that I recently built a new unRaid box from some old and new parts (new TB drives) for the primary purpose of hosting media files for my A-100 PCH.
It has worked flawlessly with one exception - because I enable the disks to spin down to save energy (and less noise), sometimes it takes a few tries for the PCH to "wake up" the disk. This is minor as it only takes a few seconds.
If you were building a new unRaid box I'd say make sure to pick a Mobo that has a proven NIC (in terms of streaming performance), but it sounds like you are purchasing a solution, in that case it should work as fast as expected (within the constraints of your switch, cables, etc).