Solutions
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Ezrael's post in Spin down working for the Array, but not for the Pools was marked as the answerHi,
I decided to do a new config for my pools, deleting all the pools and generating new ones (saving before the info of those hard drives, doing a format of them and restoring it later the data).
That seems to solve the problem. Everything is still at the same place but with the right behavior.
Thank you!