The term "Array" is old nomenclature that refers to the singular required drive pool that uses the unRAID's proprietary unRAID scheme. The "Array" pool can contain mixed drive sizes and types (though mixing SSDs and HDDs in not recommended), as well as up to 2 parity drives to maintain redundancy for the pool. unRAID also supports optional secondary drive pools (previously called cache, but weren't a cache in a typically sense of the word). These secondary pools can be single disks or have redundancy via ZFS or BTRFS software raid levels. These secondary pools are separate from the "Array" pools in terms of redundancy. In terms of file access unRAID has user shares which preset a combined view of folders from all the various drive pools. There are options to set which pool data gets written to when writing to a user share and when and if data gets moved between pools. One common usage of this is to direct all writes to an SSD pool and then have unRAID move the files onto the Array pool later.
Finally to the point above, the general recommendation is to have an SSD based pool to store appdata on, separate from the Array. Whether or not the pool used to store appdata has redundancy is up to you but it does not effect the configuration of the "Array" pool.