You can do it with the array started. Just click on the relevant shares (i.e. appadata, apps, cachetmp and downloads in your case) to change the setting.
I think that with the newer versions of unraid, the guide is a bit outdated and the setting "use disk cache" has been changed a bit. You must set the primary storage to "cache" and the secondary storage to "array".
The effect of these new settings will occur next time the mover is called, whether manually or upon schedule, meaning that all the data from these shares (currently stores only on your cache drive) will be moved to your array.