Not sure I understand what you are trying to do with this:
If you are giving Windows access to /mnt/user, then you are bypassing the security of individual Unraid user shares and just giving it all of the user shares as one share, so no separate user share security.
You should map each share separately, or better yet, don't map anything. I never "map drives" to network resources anymore, since it is simpler to just browse the network, and most applications can browse the network too so no need for "mapped drives".