In this file has the PCI devices to be bound to vfio.
root@computenode:~# cat /boot/config/vfio-pci.cfg
BIND=0000:03:00.0|8086:56a0 0000:05:00.0|8086:56a 0000:05:01.0|8086:56a0
root@computenode:~#
On my system 05:01.0 does not exist so my VMs do not auto start. So I would need to remove this. Also the vendor:product is in correct.
Take a note of your devices in tools->system devices.
Make a change to the checked devices save and then set how you want this will update the file in /boot.
So I unchecked group 20 saved, added in group 20 and now my file looks like this
root@computenode:~# cat /boot/config/vfio-pci.cfg
BIND=0000:03:00.0|8086:56a0root@computenode:~#
Changes do not take effect until a reboot.