Of course, you should always have good (enough) backups at all times.
But V6 will read (and write) your V5 disks. Your data should be fine, none of your plugins from V5 can be used. Just study the wiki linked earlier and ask if you have any questions.
One thing you might consider, though, is your V5 disks are ReiserFS. Not recommended going forward, and you will ultimately want to reformat to another filesystem, XFS is the usual for the array. So, you will have to come up with a way to empty each disk so you can reformat it. If you have enough free space you can shuffle data from one disk to other disks so you can reformat it, rinse, repeat. Or you can add a disk to get additional free space.