Your docker image is corrupt. And the fact that you have given it 80G makes me suspect you have been filling it or it has been growing. I always recommend only 20G for docker image. Making it larger will not fix anything, it will just make it take longer to fill.
Most likely you have one or more of your docker applications writing into the docker image instead of to mapped storage. If any application is writing to any path that is not in a mapped container path, then it will write into the docker image, filling it up. All applications must be configured to use paths that are absolute and correspond to a container path, case-sensitive.
Also, your cache disk is completely full, possibly that is corrupt also.
Unfortunately, your old version of Unraid doesn't give us all of the useful information about your configuration that more recent versions do. For example, I can't tell what user shares have files on your full cache. I see you have most shares set to not use cache, but I suspect you just changed them to that because you realized you were filling it. And setting them to not use cache won't get anything moved off cache.
Go to Settings - Docker, disable docker service and delete the docker image. Leave it disabled until we get room on your cache.
Go to Shares - User Shares and click the Compute All button. Wait for the result, it will likely take several minutes. Then post a screenshot of that page.