You seem to be getting continuous errors along the lines of
Jun 10 05:33:01 BIGDADDY kernel: sd 2:0:0:0: [sdb] tag#12 UNKNOWN(0x2003) Result: hostbyte=0x04 driverbyte=DRIVER_OK cmd_age=0s
Jun 10 05:33:01 BIGDADDY kernel: sd 2:0:0:0: [sdb] tag#12 CDB: opcode=0x2a 2a 00 0d f0 3f 60 00 00 40 00
Jun 10 05:33:01 BIGDADDY kernel: blk_update_request: I/O error, dev sdb, sector 233848672 op 0x1:(WRITE) flags 0x1800 phys_seg 6 prio class 0
Jun 10 05:33:01 BIGDADDY kernel: BTRFS warning (device sdd1): lost page write due to IO error on /dev/sdb1 (-5)
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Jun 10 05:33:01 BIGDADDY kernel: BTRFS error (device sdd1): error writing primary super block to device 2
Jun 10 05:33:03 BIGDADDY kernel: BTRFS warning (device sdd1): lost page write due to IO error on /dev/sdb1 (-5)
which indicates that there are issues with your cache pool since the sdd and sdb devices belong to it.
Not sure of the best way to proceed - maybe @JorgeB might have a view?