You can either create a new pool and add that SSD alone or reset the current cache and assign it there also alone, to reset cache:
Stop the array, if Docker/VM services are using the cache pool disable them, unassign all cache devices, start array to make Unraid "forget" current cache config, stop array, reassign old cache device (there can't be an "All existing data on this device will be OVERWRITTEN when array is Started" warning for any cache device), re-enable Docker/VMs if needed, start array.