That's how I like it since it keeps those from ever overflowing to the array. On the other hand, it prevents them from overflowing to the array so if you ever filled cache you would get a write failure.
I see no advantage to doing that. It would just take time and possibly present an opportunity for mistakes. There is nothing wrong with having the files spread over disks. Everything should work fine as it is as long as appdata, system, (and domains if you ever do VMs) stays on cache.
Probably the simplest way to see which plex you were using, and to check how you had it setup, is to just go ahead and enable Docker, then use the Previous Apps feature on the Apps page, launch the Add Container page for plex, then post a screenshot of that page before submitting it.