Nov 2 19:47:09 GLaDOS emhttpd: device /dev/sdf problem getting id
Nov 2 19:47:09 GLaDOS emhttpd: device /dev/sdc problem getting id
Nov 2 19:47:10 GLaDOS emhttpd: device /dev/sdg problem getting id
Nov 2 19:47:10 GLaDOS emhttpd: device /dev/sdd problem getting id
This are usually the result of having multipath to the enclosure enable, Unraid doesn't support that, use a single cable from the HBA to the enclosure.
Btrfs errors are the result of the device dropping offline, try using a different cables/slot or controller for the cache device.