Both images are corrupt, you'll need to recreate them, libvirt should be restored from a backup if available or you'll lose the XML for the VMs , corruption most likely caused by one of you cache drives (cache1) dropping out in the past:
Jun 26 15:38:58 unraid kernel: BTRFS info (device sdk1): bdev /dev/sdk1 errs: wr 469514164, rd 255940664, flush 10036587, corrupt 0, gen 0
These are read and writes errors, and a lot of them so it dropped out for some time, or multiple times, see here for more info on how to better monitor a pool.