Some of that might be connection issues, but there are these mixed in:
Jul 28 18:29:04 vault kernel: ata6.00: cmd 25/00:28:a8:08:72/00:03:06:00:00/e0 tag 5 dma 413696 in
Jul 28 18:29:04 vault kernel: res 51/40:17:b0:09:72/00:02:06:00:00/e0 Emask 0x9 (media error)
Also, this SMART attribute is something to watch out for on WD Reds, in fact, I have it added to the notifications for those disks I have:
ID# ATTRIBUTE_NAME FLAGS VALUE WORST THRESH FAIL RAW_VALUE
1 Raw_Read_Error_Rate POSR-K 200 200 051 - 266
Do you have a replacement?