Sep 9 15:01:30 Tower emhttpd: /mnt/cache ERROR: cannot scan /dev/sdf1: Input/output error
This is the problem, sdf is parity and because you have an odd number of btrfs arrays devices makes it look like parity has an invalid btrfs filesystem and causes issues during btrfs device scan, it's a known issue but there's no fix for now, workaround is to use xfs only for the array, use btrfs encrypted, or have an even number of btrfs array devices, this last option usually works but not always.