Some configs have issues with free space, as is reported by df or statfs as you can see above (Unraid uses statfs), this happens for example with an odd number of devices in raid1 and apparently also happens with raid10 when not using multiples of 4 devices, you still have 3TB of usable space, as reported by btrfs fi usage, and as the pool gets filled free space should also get closer to correct, i.e., when you have 2TB used it should show close to 1TB free.