x4 PCIe 2.0 slot is still good for 2000MB/s (around 1600MB/s usable), so yes, it's enough, though note that the bottom one is shared with the DMI and anything using it, like the onboard SATA ports, if they are being used.
FYI log is filled with ATA errors, on multiple disks, and parity is disable, but for now try runing xfs_repair manually, start array in maintenance mode and post output of:
xfs_repair -nv /dev/md6