Pool fs is fully allocated, you need to run a balance, see here for more info, king of strange this is happening in a new filesystem, did you fill it up completely before?
Two of the Asmedia 6/10 port controllers you're using are a 2 port controller with SATA port multipliers that have various known issues, don't use those with Unraid.
Also, why are you not using the Intel SATA ports, those are rock solid.