Sure, set that share to cache only.
Yes, shares can have folders on multiple array drives and pools. You would set the share to cache: no if you wanted new files to be written to the array, or cache: only if you wanted new files to be written to cache. Mover ignores cache no and only.
Yes. When you add new drives the parity will no longer be a mirror, but it will still allow the reconstruction of a single failed drive as long as the other data drives are ok.
Previous versions of Unraid only allowed 1 pool, and it was always called cache. The ability to set up multiple pools is new, as is the ability to name them differently. The usage is still the same.
There is a restriction on automatic scheduled moves, each share can only have 1 pool assigned for scheduled movement, but if you manually put files on a different specific pool in a root folder, that folder is still part of the user share with that name.
Shares with cache: yes and cache: prefer will move files between their assigned pool and the main array when the mover schedule dictates.