Off the top of my head for a stock install, the flash drive on /boot, array disks in /mnt/disk(X), named pools in /mnt, docker image in /var/lib/docker, VM image in /etc/libvirt. Pretty much anything else is user added, like /mnt/disks/* and /mnt/remotes/* for Unassigned devices.
Use the df command to see what all is available.
Since /boot is FAT, there are restrictions because FAT doesn't honor all permissions. The mount points are available at different times based on what is started and what isn't, so if you need access without the array started you are limited.