Problems with one of the cache devices:
Sep 20 21:56:52 NAS kernel: sd 0:0:0:0: timing out command, waited 360s
Sep 20 21:56:52 NAS kernel: sd 0:0:0:0: [sda] tag#0 UNKNOWN(0x2003) Result: hostbyte=0x00 driverbyte=0x08
Sep 20 21:56:52 NAS kernel: sd 0:0:0:0: [sda] tag#0 Sense Key : 0x4 [current]
Sep 20 21:56:52 NAS kernel: sd 0:0:0:0: [sda] tag#0 ASC=0x44 ASCQ=0x0
Sep 20 21:56:52 NAS kernel: sd 0:0:0:0: [sda] tag#0 CDB: opcode=0x35 35 00 00 00 00 00 00 00 00 00
Sep 20 21:56:52 NAS kernel: print_req_error: I/O error, dev sda, sector 0
Sep 20 21:56:52 NAS kernel: BTRFS error (device sda1): bdev /dev/sda1 errs: wr 16, rd 0, flush 17, corrupt 0, gen 0
USB it not recommended for cache or array devices.