On the main page click on Shares, then appdata, there you can select the "use cache" option, good idea to turn the help on so you understand the different behavior of each option, it should already be set to cache=prefer which is what you want.
After checking that you can run the mover, first disable the docker service (settings -> docker), all dockers will be stopped, then run the mover, that's on the main page below the start/stop array buttons, after it's done check that appdata only exists on cache now, you can also check that on the shares page by clicking on "compute" size on the appdate share (note that any existing files with the same name on cache would prevent the others being moved).