What makes you think it should have been used?
As far as I can see your shares are set to use Highwater allocation method. Since your largest disks are 10TB, the disks start switching at 5TB, 2.5TB, 1.25TB etc. On this basis disk11 will not start getting used until all the lower numbered disks have less than 2.5TB free (which is not currently the case as disk1 and disk2 have more than that free).