Not worked out from the diagnostics what the current issue is, but I do notice a few anomalies with your shares:
Share that is anonymised as N-------d has files on disk1 and disk2 even though it has an Include setting for only disk2. That setting applies to new files, but I suspect at some time in the past disk1 was also allowed and those files are left there. You would need to manually move folder/files from disk1 to disk2 to tidy this up.
The 'appdata' share has files on both cache and disk1 although it is now set to only use 'cache' pool for new files. With that setting any existing files on other drives are left there. You want the files on disk1 to be moved to cache for optimum performance and to take advantage of the 'appdata' share then becoming an Exclusive share for better performance (if you enable this under Settings->Global Share settings).