Sep 28 11:50:56 Ascension emhttpd: shcmd (520): mount -t btrfs -o noatime,space_cache=v2 /dev/sdc1 /mnt/cache
Sep 28 11:50:56 Ascension root: mount: /mnt/cache: wrong fs type, bad option, bad superblock on /dev/sdc1, missing codepage or helper program, or other error.
Your cache is not mounting, and no valid btrfs filesystem in being found on boot, are you sure it was btrfs?
You are using a raid volume, that might be the part of the problem, it might have change something:
import 30 cache device: (sdc) LOGICAL_VOLUME_5001438016327E90_3600508b1001c52ba5e10bd5d90a2e4dc